Step 1: Recall packing efficiency.
Packing efficiency is the fraction of the total volume of the unit cell that is actually occupied by the constituent particles (atoms/ions).
Step 2: fcc crystal characteristics.
In a face-centered cubic (fcc) unit cell:
Number of atoms per unit cell \(= 4\).
Atoms touch along the face diagonal.
Step 3: Standard result.
For fcc structure, the packing efficiency has a well-known calculated value of \(\approx 74%\).
Step 4: Conclusion.
The packing efficiency of an fcc crystal structure is \(74.0%\).