Step 1: Use the formula for molarity.
The formula for molarity is:
\[
M = \frac{\text{moles of solute}}{\text{volume of solution in dm}^3}
\]
First, calculate the moles of NaOH:
\[
\text{moles of NaOH} = \frac{\text{mass of NaOH}}{\text{molar mass of NaOH}} = \frac{3.2 \, \text{g}}{40 \, \text{g/mol}} = 0.08 \, \text{mol}
\]
Step 2: Convert volume to dm\(^3\).
The volume is 250 cm\(^3\), which is equal to:
\[
\text{Volume in dm}^3 = \frac{250}{1000} = 0.25 \, \text{dm}^3
\]
Step 3: Calculate molarity.
\[
M = \frac{0.08 \, \text{mol}}{0.25 \, \text{dm}^3} = 0.32 \, \text{mol dm}^{-3}
\]
Step 4: Conclusion.
The molarity of the solution is 0.32 mol dm\(^{-3}\).