Step 1: Number of atoms in fcc unit cell.
A face centered cubic (fcc) unit cell contains 4 atoms per unit cell.
Step 2: Mass of one atom.
Mass of one atom is given as $6 \times 10^{-23}$ g.
Step 3: Calculate mass of unit cell.
\[
\text{Mass of unit cell} = 4 \times 6 \times 10^{-23}
\]
\[
= 24 \times 10^{-23} = 2.4 \times 10^{-22}\ \text{g}
\]
Step 4: Conclusion.
Hence, the mass of one fcc unit cell is $2.4 \times 10^{-22}$ g.