Copper deviates from the expected configuration \( [\text{Ar}] 3d^9 4s^2 \) to achieve greater stability with a completely filled \( 3d \)-subshell. The actual configuration is:
\[
[\text{Ar}] 3d^{10} 4s^1.
\]
This arrangement lowers the energy of the atom due to the enhanced stability of a completely filled \( d \)-subshell.
---
Final Answer:
\[
\boxed{[\text{Ar}] 3d^{10} 4s^1}
\]