What is the effect of temperature on the rate constant of a reaction?
The rate constant of a reaction generally increases with temperature. This is explained by the Arrhenius equation, which shows that the rate constant \(k\) increases exponentially with an increase in temperature. As the temperature rises, the number of molecules having sufficient energy to overcome the activation energy barrier increases, leading to an increase in the rate constant. \[ k = A \cdot e^{-\frac{E_a}{RT}} \] Where: - \(k\) is the rate constant, - \(A\) is the frequency factor, - \(E_a\) is the activation energy, - \(R\) is the gas constant, - \(T\) is the temperature in Kelvin.
The conversion of molecule X to Y follows second-order kinetics. If the concentration of X is increased 3 times, how will it affect the rate of formation of Y?
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.