Glycogen is a carbohydrate (polysaccharide). In animals, carbohydrates are stored as glycogen.
Starch is a carbohydrate consisting of two components - amylose (15 - 20%) and amylopectin (80 - 85%).
However, glycogen consists of only one component whose structure is similar to amylopectin. Also, glycogen is more branched than amylopectin.
Polysaccharides are the most abundant hydrocarbons that exist in our food. They are long chains of hydrocarbons inclusive of smaller units called monosaccharides or monomers, related to each other through glycosidic linkages. Cellulose, starch, chitin, and glycogen are the most common polysaccharides found in food.