When atoms and molecules vibrate, they produce electromagnetic radiation primarily in the infrared (IR) region of the spectrum. The vibration of the bonds between atoms in a molecule leads to the absorption or emission of infrared radiation.
- Microwaves are associated with rotational transitions in molecules.
- Ultraviolet (UV) radiation is related to electronic transitions.
- Infrared (IR) radiation corresponds to the vibrational modes of atoms and molecules.
Thus, the correct answer is Infrared radiation.