We are given two thermally insulated identical vessels A and B, connected through a stopcock. Vessel A contains a gas at STP (Standard Temperature and Pressure), and vessel B is completely evacuated. When the stopcock is suddenly opened, the gas expands into vessel B. We need to analyze what happens to the temperature, pressure, and internal energy of the gas.
In this situation, the key concepts to consider are:
In free expansion of an ideal gas:
Therefore, the internal energy remains the same, but the pressure decreases.
Correct Answer: (E) internal energy remains the same
The standard heat of formation, in kcal/mol, of $Ba^{2+}$ is:
Given: Standard heat of formation of SO₄²⁻(aq) = -216 kcal/mol, standard heat of crystallization of BaSO₄(s) = -4.5 kcal/mol, standard heat of formation of BaSO₄(s) = -349 kcal/mol.