Through polariser \( P_2 \), the intensity \( I_1 \) of the transmitted light is given by:
\[
I_1 = I_0 \cos^2 \theta
\]
where \( \theta \) is the angle between the light incident on \( P_2 \) and the polariser axis.
Next, through \( P_3 \), the intensity \( I_{\text{net}} \) becomes:
\[
I_{\text{net}} = I_0 \cos \theta \sin \theta
\]
To maximize the transmitted intensity, we set the angle \( \theta \) such that the product \( \sin(2\theta) \) is maximized. This occurs when:
\[
\sin(2\theta) = 1 \quad \text{for} \quad \theta = 45^\circ
\]
Thus, the angle between \( P_2 \) and \( P_3 \) is \( \frac{\pi}{4} \).