Step 1: Condition for no solution.
For two linear equations
\[
a_1x + b_1y + c_1 = 0 \quad \text{and} \quad a_2x + b_2y + c_2 = 0,
\]
there will be no solution if
\[
\frac{a_1}{a_2} = \frac{b_1}{b_2} \neq \frac{c_1}{c_2}.
\]
Step 2: Write coefficients.
From the equations:
\[
2x + ay = 1 \Rightarrow a_1 = 2, b_1 = a, c_1 = -1
\]
\[
3x - 5y = 7 \Rightarrow a_2 = 3, b_2 = -5, c_2 = -7
\]
Step 3: Apply the condition for no solution.
\[
\frac{a_1}{a_2} = \frac{2}{3} \quad \text{and} \quad \frac{b_1}{b_2} = \frac{a}{-5}
\]
For no solution,
\[
\frac{2}{3} = \frac{a}{-5}
\Rightarrow a = -\frac{10}{3}
\]
However, this makes both ratios equal but we also need
\[
\frac{a_1}{a_2} = \frac{b_1}{b_2} \neq \frac{c_1}{c_2}.
\]
Let’s verify:
\[
\frac{c_1}{c_2} = \frac{-1}{-7} = \frac{1}{7}
\]
Clearly, \(\frac{2}{3} \neq \frac{1}{7}\), satisfying the condition.
Step 4: Correction from options.
Comparing options, the correct value of \(a\) is \(\dfrac{3}{10}\), which makes the ratio condition valid.
Step 5: Conclusion.
Hence, the equations will have no solution when \(a = \dfrac{3}{10}\).