The wavelength \( \lambda \) of a photon can be calculated using the energy-wavelength relationship:
E = \( \frac{hc}{\lambda} \)
Where:
We can rearrange the formula to solve for the wavelength \( \lambda \):
\( \lambda = \frac{hc}{E} \)
Given that the energy of the γ-ray is 0.66 MeV, we first need to convert this to joules:
\(E = 0.66 \, \text{MeV} \times 1.602 \times 10^{-13} \, \text{J/MeV} = 1.0573 \times 10^{-13} \, \text{J}\)
Now, substitute the values into the equation for \( \lambda \):
\(\lambda = \frac{(6.626 \times 10^{-34} \, \text{J.s})(2.998 \times 10^8 \, \text{m/s})}{1.0573 \times 10^{-13} \, \text{J}}\)
\(\lambda = 0.021 \, \text{Å}\)
Thus, the wavelength of the γ-ray is 0.021 Å (rounded to three decimal places).
The UV-visible spectrum of [Ni(en)\(_3\)]\(^{2+}\) (en = ethylenediamine) shows absorbance maxima at 11200 cm\(^{-1}\), 18350 cm\(^{-1}\), and 29000 cm\(^{-1}\).
[Given: Atomic number of Ni = 28] The correct match(es) between absorbance maximum and electronic transition is/are
Compound K displayed a strong band at 1680 cm−1 in its IR spectrum. Its 1H-NMR spectral data are as follows:
δ (ppm):
7.30 (d, J = 7.2 Hz, 2H)
6.80 (d, J = 7.2 Hz, 2H)
3.80 (septet, J = 7.0 Hz, 1H)
2.20 (s, 3H)
1.90 (d, J = 7.0 Hz, 6H)
The correct structure of compound K is:
The 1H NMR spectrum of the given iridium complex at room temperature gave a single signal at 2.6 ppm, and its 31P NMR spectrum gave a single signal at 23.0 ppm. When the spectra were recorded at lower temperatures, both these signals split into a complex pattern. The intra-molecular dynamic processes shown by this molecule are: