We are given the expression \( (1 + i)^{12} \), where \( i = \sqrt{-1} \).
Step 1: Convert to polar form.
First, express \( 1 + i \) in polar form. The modulus of \( 1 + i \) is given by: \[ |1 + i| = \sqrt{1^2 + 1^2} = \sqrt{2}. \] The argument \( \theta \) of \( 1 + i \) is: \[ \theta = \tan^{-1}\left(\frac{1}{1}\right) = \frac{\pi}{4}. \] Thus, we can write: \[ 1 + i = \sqrt{2} \left( \cos\left(\frac{\pi}{4}\right) + i \sin\left(\frac{\pi}{4}\right) \right). \]
Step 2: Apply De Moivre's Theorem.
Using De Moivre's Theorem, we raise the expression to the 12th power: \[ (1 + i)^{12} = \left( \sqrt{2} \right)^{12} \left( \cos\left( 12 \times \frac{\pi}{4} \right) + i \sin\left( 12 \times \frac{\pi}{4} \right) \right). \] This simplifies to: \[ (1 + i)^{12} = 2^6 \left( \cos\left( 3\pi \right) + i \sin\left( 3\pi \right) \right). \] Since \( \cos(3\pi) = -1 \) and \( \sin(3\pi) = 0 \), we have: \[ (1 + i)^{12} = 64(-1 + 0i) = -64. \]

An ideal monoatomic gas is contained inside a cylinder-piston assembly connected to a Hookean spring as shown in the figure. The piston is frictionless and massless. The spring constant is 10 kN/m. At the initial equilibrium state (shown in the figure), the spring is unstretched. The gas is expanded reversibly by adding 362.5 J of heat. At the final equilibrium state, the piston presses against the stoppers. Neglecting the heat loss to the surroundings, the final equilibrium temperature of the gas is __________ K (rounded off to the nearest integer).
The residence-time distribution (RTD) function of a reactor (in min$^{-1}$) is 
The mean residence time of the reactor is __________ min (rounded off to 2 decimal places).}
Ideal nonreacting gases A and B are contained inside a perfectly insulated chamber, separated by a thin partition, as shown in the figure. The partition is removed, and the two gases mix till final equilibrium is reached. The change in total entropy for the process is _________J/K (rounded off to 1 decimal place).
Given: Universal gas constant \( R = 8.314 \) J/(mol K), \( T_A = T_B = 273 \) K, \( P_A = P_B = 1 \) atm, \( V_B = 22.4 \) L, \( V_A = 3V_B \).
The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:
\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is __________ MPa (rounded off to 3 decimal places).