The residence-time distribution (RTD) function of a reactor (in min$^{-1}$) is 
The mean residence time of the reactor is __________ min (rounded off to 2 decimal places).}
Step 1: Understand the RTD Function.
The RTD function is defined piecewise, with a linear decrease from 1 to 0 as time increases from 0 to 0.5 minutes and 0 thereafter.
Step 2: Calculate the Mean Residence Time.
The mean residence time $\tau$ can be calculated using the integral of $t \cdot E(t)$ over the effective time range: \[ \tau = \int_0^\infty t \cdot E(t) \, dt = \int_0^{0.5} t \cdot (1 - 2t) \, dt \] \[ \tau = \int_0^{0.5} (t - 2t^2) \, dt = \left[ \frac{t^2}{2} - \frac{2t^3}{3} \right]_0^{0.5} \] \[ \tau = \left( \frac{0.5^2}{2} - \frac{2(0.5)^3}{3} \right) = \frac{0.25}{2} - \frac{0.25}{3} \] \[ \tau = \frac{0.125 - 0.0833}{1} = 0.0417 { min} \] The mean residence time of the reactor is $0.042$ min, which is approximately $2.5$ seconds, rounding off to two decimal places.
Which element of the 3d series has the lowest enthalpy of atomisation and why?
Methanol is produced by the reversible, gas-phase hydrogenation of carbon monoxide: \[ {CO} + 2{H}_2 \rightleftharpoons {CH}_3{OH} \] CO and H$_2$ are charged to a reactor, and the reaction proceeds to equilibrium at 453 K and 2 atm. The reaction equilibrium constant, which depends only on the temperature, is 1.68 at the reaction conditions. The mole fraction of H$_2$ in the product is 0.4. Assuming ideal gas behavior, the mole fraction of methanol in the product is ____________ (rounded off to 2 decimal places).
Choose the option that correctly matches the items in Group 1 with those in Group 2.

An ideal monoatomic gas is contained inside a cylinder-piston assembly connected to a Hookean spring as shown in the figure. The piston is frictionless and massless. The spring constant is 10 kN/m. At the initial equilibrium state (shown in the figure), the spring is unstretched. The gas is expanded reversibly by adding 362.5 J of heat. At the final equilibrium state, the piston presses against the stoppers. Neglecting the heat loss to the surroundings, the final equilibrium temperature of the gas is __________ K (rounded off to the nearest integer).
Ideal nonreacting gases A and B are contained inside a perfectly insulated chamber, separated by a thin partition, as shown in the figure. The partition is removed, and the two gases mix till final equilibrium is reached. The change in total entropy for the process is _________J/K (rounded off to 1 decimal place).
Given: Universal gas constant \( R = 8.314 \) J/(mol K), \( T_A = T_B = 273 \) K, \( P_A = P_B = 1 \) atm, \( V_B = 22.4 \) L, \( V_A = 3V_B \).
The following data is given for a ternary \(ABC\) gas mixture at 12 MPa and 308 K:
\(y_i\): mole fraction of component \(i\) in the gas mixture
\(\hat{\phi}_i\): fugacity coefficient of component \(i\) in the gas mixture at 12 MPa and 308 K
The fugacity of the gas mixture is __________ MPa (rounded off to 3 decimal places).