According to the photoelectric equation:
\[
E_k = h(f - v)
\]
where \( E_k \) is the kinetic energy of the emitted photoelectrons, \( f \) is the frequency of the incident photons, and \( v \) is the threshold frequency.
The maximum linear momentum \( P \) is related to the kinetic energy \( E_k \) by the equation:
\[
E_k = \frac{P^2}{2m}
\]
where \( m \) is the mass of the photoelectron.
For photoelectrons to have maximum linear momentum \( 2P \), the frequency of the incident photons must be increased. By analyzing the relationship between frequency and momentum, we determine that the frequency of the photons should be \( 5v \) to achieve the required momentum.
Thus, the correct answer is \( \boxed{5v} \).