Even though monochromatic light (single frequency) has photons of the same energy, photoelectrons are emitted from different depths of the metal surface. Those emitted from deeper layers lose some energy in overcoming internal resistance and collisions with atoms before reaching the surface.
Therefore, the kinetic energy of photoelectrons is given by:
\( K.E. = h\nu - \phi - \text{energy lost inside the metal} \)
Hence, photoelectrons do not have identical kinetic energies.
Saturation current corresponds to the maximum photocurrent when all emitted electrons are collected. As the intensity of light increases, more photons are incident on the metal per unit time, resulting in the emission of more photoelectrons.
Since current is directly proportional to the number of electrons, saturation current increases with light intensity.
The energy of a photon is given by:
\( E = \frac{hc}{\lambda} \)
As the wavelength \( \lambda \) increases, the energy \( E \) of each photon decreases. When \( \lambda \) becomes large enough that \( E \lt \phi \) (work function of the metal), photons no longer have enough energy to eject electrons.
Hence, photoemission stops beyond a certain cut-off wavelength \( \lambda_0 \), where:
\( \lambda_0 = \frac{hc}{\phi} \)
Einstein's Explanation of the Photoelectric Effect:
Einstein explained the photoelectric effect on the basis of Planck’s quantum theory, where light travels in the form of small bundles of energy called photons.
The energy of each photon is hν, where:
The number of photons in a beam of light determines the intensity of the incident light.When a photon strikes a metal surface, it transfers its total energy hν to a free electron in the metal.A part of this energy is used to eject the electron from the metal, and this required energy is called the work function.The remaining energy is carried by the ejected electron as its kinetic energy.
In the given reaction sequence, the structure of Y would be: