Step 1: Understanding Chemical Applications
- Chloroform (\( CHCl_3 \)) is used in the production of Freon-12 (\( CCl_2F_2 \)), a refrigerant.
- Carbon tetrachloride (\( CCl_4 \)) is not used in Freon-22 production (incorrect).
- Dichloromethane (\( CH_2Cl_2 \)) is not used as a propellant (incorrect).
- DDT is an insecticide, but not the first chlorinated herbicide (incorrect).
Conclusion
Thus, the correct answer is:
\[
CHCl_3 \text{ - used in production of Freon-12}
\]