Step 1: The terminal potential difference \( V \) is related to the emf \( E \), the internal resistance \( r \), and the external resistance \( R \) by: \[ V = E - I r \] where \( I \) is the current.
Step 2: The current \( I \) is: \[ I = \frac{E}{R + r} \] Substitute this into the equation for \( V \): \[ V = E - \frac{E r}{R + r} \] Step 3: Given \( E = 2 \, {V} \), \( V = 1.5 \, {V} \), and \( R = 10 \, \Omega \), we can solve for \( r \): \[ 1.5 = 2 - \frac{2r}{10 + r} \] Step 4: Solving for \( r \): \[ 0.5 = \frac{2r}{10 + r} \quad \Rightarrow \quad 0.5(10 + r) = 2r \quad \Rightarrow \quad 5 + 0.5r = 2r \] \[ 5 = 1.5r \quad \Rightarrow \quad r = \frac{10}{3} \, \Omega \] Thus, the internal resistance of the cell is \( \frac{10}{3} \, \Omega \).
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: