Step 1: The de-Broglie wavelength \( \lambda \) for a particle is given by: \[ \lambda = \frac{h}{p} \] where \( p \) is the momentum of the particle.
Step 2: For a proton, \( p = mv \), where \( m \) is the mass and \( v \) is the velocity of the proton. For a photon, \( p = \frac{E}{c} \), where \( E \) is the energy and \( c \) is the speed of light.
Step 3: Since both the proton and the photon have the same energy, we can relate their wavelengths using their respective momenta. For the photon, the wavelength is inversely proportional to the momentum, while for the proton, the momentum is proportional to its velocity.
Thus, the de-Broglie wavelength of the proton and photon are related by: \[ \lambda_0 \propto \lambda_p^2 \]
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: