Question:

The sol formed in the following unbalanced equation is:
\[ As_2O_3 + H_2S \rightarrow {?} \]

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Colloidal sols can form from precipitation reactions involving metal oxides and hydrogen sulfide.
Updated On: May 22, 2025
  • As$_2$S$_2$
  • As$_2$S$_3$
  • As
  • S
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The Correct Option is B

Approach Solution - 1

Step 1: Identify the Reaction Type 
The reaction involves arsenic(III) oxide reacting with hydrogen sulfide to form arsenic sulfide (\( As_2S_3 \)). 
Step 2: Balancing the Reaction 
\[ As_2O_3 + 3H_2S \rightarrow As_2S_3 + 3H_2O \] Here, arsenic oxide is reduced to arsenic sulfide while hydrogen sulfide is oxidized. 
Final Answer: The sol formed in this reaction is arsenic sulfide (\( As_2S_3 \)).

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Approach Solution -2

The sol formed in the reaction between arsenic(III) oxide and hydrogen sulfide is arsenic trisulfide (As2S3):

When arsenic(III) oxide (As2O3) reacts with hydrogen sulfide (H2S), a double displacement reaction occurs, leading to the formation of arsenic trisulfide (As2S3), which is an insoluble colloidal substance known as a sol.

This sol is a typical example of a sulfur compound precipitate that forms as a colloidal dispersion in water.

The unbalanced reaction is:
As2O3 + H2S → As2S3 + H2O

Here, As2S3 is the characteristic yellow-orange sol formed.

Such reactions are important in qualitative inorganic analysis to identify arsenic compounds through their sulfide precipitates.
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