Step 1: Understanding body-centred cubic (BCC) unit cell.
In a body-centred cubic (BCC) unit cell, atoms are located at the eight corners and at the center of the cell. The space not occupied by the atoms is free space.
Step 2: Calculation of free space.
- The volume of the BCC unit cell is determined by the length of its edge and the volume of the atoms inside it.
- The percentage of free space is calculated by comparing the total volume of the unit cell to the volume occupied by the atoms.
The percentage of free space in a BCC unit cell is approximately 28%.
Final Answer:
\[
\boxed{28}
\]