Question:

The Radial Probability curve for 2s orbital.

Updated On: Aug 16, 2023
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Solution and Explanation

The radial probability distribution curve for a 2s orbital illustrates the probability of finding an electron at various distances from the nucleus in a hydrogen atom or a hydrogen-like ion. The shape of the curve is influenced by the mathematical expression that describes the behavior of the 2s orbital.

For a hydrogen-like atom (like hydrogen itself or singly ionized helium), the radial probability distribution function P(r)) for the 2s orbital can be expressed as:

P(r)=4πr2R2s2​(r)

Here, r represents the radial distance from the nucleus, and R2s2​(r) is the radial wavefunction for the 2s orbital.

The general trend of the radial probability curve for a 2s orbital is as follows:

  1. The probability is highest near the nucleus (at r=0).
  2. The probability decreases as you move away from the nucleus.
  3. The probability drops to zero as the distance from the nucleus becomes very large.

Visually, the curve starts at a maximum value at r=0, and then it gradually decreases as r increases. The curve reflects the fact that the probability of finding the electron is most likely near the nucleus and becomes progressively less likely as you move farther away.

It's important to note that the specific shape of the curve is influenced by the mathematical details of the 2s orbital's wavefunction, but the general trends described above apply to all s-type orbitals.

 

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Concepts Used:

Structure of Atom

Atomic Structure:

The atomic structure of an element refers to the constitution of its nucleus and the arrangement of the electrons around it. Primarily, the atomic structure of matter is made up of protons, electrons and neutrons.

Dalton’s Atomic Theory

Dalton proposed that every matter is composed of atoms that are indivisible and indestructible. 

The following are the postulates of his theory:

  • Every matter is made up of atoms.
  • Atoms are indivisible.
  • Specific elements have only one type of atoms in them.
  • Each atom has its own constant mass that varies from element to element.
  • Atoms undergo rearrangement during a chemical reaction.
  • Atoms can neither be created nor be destroyed but can be transformed from one form to another.

Cons of Dalton’s Atomic Theory

  • The theory was unable to explain the existence of isotopes.
  • Nothing about the structure of atom was appropriately explained.
  • Later, the scientists discovered particles inside the atom that proved, the atoms are divisible.

​​Subatomic Particles

  1. Protons - are positively charged subatomic particles.
  2. Electron - are negatively  charged subatomic particles.
  3. Neutrons - are electrically neutral particles and carry no charge

Atomic Structure of Isotopes

Several atomic structures of an element can exist, which differ in the total number of nucleons.These variants of elements having a different nucleon number (also known as the mass number) are called isotopes of the element. Therefore, the isotopes of an element have the same number of protons but differ in the number of neutrons.  For example, there exist three known naturally occurring isotopes of hydrogen, namely, protium, deuterium, and tritium.