Photochemical smog is a type of air pollution that primarily consists of nitrogen oxides (NO\(_x\)) and volatile organic compounds (VOCs) that react under the influence of sunlight to form secondary pollutants, including ozone (O\(_3\)), formaldehyde (HCHO), and peroxyacetyl nitrates (PANs). Step 1: In the formation of photochemical smog, nitrogen oxides like NO and NO\(_2\) play a crucial role, along with VOCs. These pollutants lead to the formation of ozone and other harmful compounds.
Step 2: SO\(_2\) (sulfur dioxide) is typically associated with industrial smog (or ``London-type smog"), which is different from photochemical smog.
It does not generally participate in the formation of photochemical smog under normal sunlight conditions.
Step 3: Therefore, SO\(_2\) is not generally present in photochemical smog, unlike NO, NO\(_2\), and HCHO, which are key components.