The P-V diagram of an engine is shown in the figure below. The temperatures at points 1, 2, 3 and 4 are T1, T2, T3 and T4, respectively. 1→2 and 3→4 are adiabatic processes, and 2→3 and 4→1 are isochoric processes
Identify the correct statement(s).
[γ is the ratio of specific heats Cp (at constant P) and Cv (at constant V)]
Apply the adiabatic and isochoric process relations.
1. Adiabatic Process Relationships:
- For \(1 \to 2\) (adiabatic process): \(T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}.\)
- For \(3 \to 4\) (adiabatic process): \(T_3 V_3^{\gamma - 1} = T_4 V_4^{\gamma - 1}.\)
- For adiabatic processes, pressure and temperature are related as: \(T_1 T_3 = T_2 T_4.\)
Hence, statement (A) is correct.
2. Efficiency of the Engine:
- The efficiency of a heat engine operating on a cycle is given by:
\(\eta = 1 - \frac{Q_{{out}}}{Q_{{in}}}\), where \(Q_{{out}}\) and \(Q_{{in}}\) are the heat rejected and absorbed, respectively.
- For this cycle, the efficiency can also be expressed using the pressure ratio for adiabatic processes as: \(\eta = 1 - \left(\frac{P_1}{P_2}\right)^{\frac{\gamma - 1}{\gamma}}.\)
Hence, statement (B) is correct.
3. Entropy Change:
- For the entire cyclic process, the system returns to its initial state. As entropy is a state function, the total entropy change over a complete cycle is zero: \(\Delta S_{{cycle}} = 0\).
Hence, statement (C) is correct.
4. Temperature Relationship:
- The relationship \(T_1 T_2 = T_3 T_4\) is incorrect as it does not align with the conditions for adiabatic and isochoric processes.
Hence, statement (D) is incorrect.
The molarity of a 70% (mass/mass) aqueous solution of a monobasic acid (X) is:
Given below are some nitrogen containing compounds:
Each of them is treated with HCl separately. 1.0 g of the most basic compound will consume ....... mg of HCl.
(Given Molar mass in g mol\(^{-1}\): C: 12, H: 1, O: 16, Cl: 35.5.)