The P-V diagram of an engine is shown in the figure below. The temperatures at points 1, 2, 3 and 4 are T1, T2, T3 and T4, respectively. 1→2 and 3→4 are adiabatic processes, and 2→3 and 4→1 are isochoric processes
Identify the correct statement(s).
[γ is the ratio of specific heats Cp (at constant P) and Cv (at constant V)]
Apply the adiabatic and isochoric process relations.
1. Adiabatic Process Relationships:
- For \(1 \to 2\) (adiabatic process): \(T_1 V_1^{\gamma - 1} = T_2 V_2^{\gamma - 1}.\)
- For \(3 \to 4\) (adiabatic process): \(T_3 V_3^{\gamma - 1} = T_4 V_4^{\gamma - 1}.\)
- For adiabatic processes, pressure and temperature are related as: \(T_1 T_3 = T_2 T_4.\)
Hence, statement (A) is correct.
2. Efficiency of the Engine:
- The efficiency of a heat engine operating on a cycle is given by:
\(\eta = 1 - \frac{Q_{{out}}}{Q_{{in}}}\), where \(Q_{{out}}\) and \(Q_{{in}}\) are the heat rejected and absorbed, respectively.
- For this cycle, the efficiency can also be expressed using the pressure ratio for adiabatic processes as: \(\eta = 1 - \left(\frac{P_1}{P_2}\right)^{\frac{\gamma - 1}{\gamma}}.\)
Hence, statement (B) is correct.
3. Entropy Change:
- For the entire cyclic process, the system returns to its initial state. As entropy is a state function, the total entropy change over a complete cycle is zero: \(\Delta S_{{cycle}} = 0\).
Hence, statement (C) is correct.
4. Temperature Relationship:
- The relationship \(T_1 T_2 = T_3 T_4\) is incorrect as it does not align with the conditions for adiabatic and isochoric processes.
Hence, statement (D) is incorrect.
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)]
A sample of n-octane (1.14 g) was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is 5 kJ K\(^{-1}\). As a result of combustion, the temperature of the calorimeter increased by 5 K. The magnitude of the heat of combustion at constant volume is ___