Total Cases:
\[ 3^{20} \]
Subtracting Invalid Cases:
Final Calculation:
\[ \text{Total} - (\text{One child receives no orange} + \text{Two children receive no orange}) \]
\[ = 3^{20} - \binom{3}{1} \cdot 2^{20 - 2} + \binom{3}{2} \cdot 1^{20} \]
\[ = 3483638676 \]
Total number of nucleophiles from the following is: \(\text{NH}_3, PhSH, (H_3C_2S)_2, H_2C = CH_2, OH−, H_3O+, (CH_3)_2CO, NCH_3\)