Question:

The number of \(\sigma\) bonds, \(\pi\)-bonds, and lone pairs of electrons present in the product Z in the given reaction sequence are respectively: 

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The presence of metals in organic reactions often hints at complex formation or coordination chemistry, which may alter typical bonding patterns seen in simpler organic molecules.
Updated On: Mar 19, 2025
  • 9, 1, 0
  • 9, 0, 2
  • 8, 2, 1
  • 9, 1, 2
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The Correct Option is D

Solution and Explanation

Step 1: Understanding the reaction mechanism.

1. The given reaction starts with 1,2-dibromoethane, which undergoes zinc reduction to form ethene (C\(_2\)H\(_4\)).

2. In the presence of \( \text{H}^+ \)/H\(_2\)SO\(_4\), ethene undergoes rearrangement, leading to the formation of cyclopropane derivatives.

3. The final step involves heating with Cu at 573K, which facilitates further rearrangement leading to a conjugated system containing \( \sigma \) and \( \pi \) bonds, as well as lone pairs on heteroatoms.

Step 2: Counting the bonds and lone pairs.

\( \sigma \) bonds: 9

\( \pi \) bonds: 1

Lone pairs: 2

Thus, the correct answer is (4) 9, 1, 2.

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