Step 1: Write the neutralization equation.
The neutralization reaction between \( \text{NaOH} \) and \( \text{HCl} \) is:
\[
\text{NaOH} + \text{HCl} \rightarrow \text{NaCl} + \text{H}_2\text{O}
\]
From the equation, we see that \( 1 \, \text{mol} \) of \( \text{NaOH} \) neutralizes \( 1 \, \text{mol} \) of \( \text{HCl} \).
Step 2: Use the formula for titration.
The formula for titration is:
\[
C_1 V_1 = C_2 V_2
\]
Where:
- \( C_1 \) and \( V_1 \) are the concentration and volume of \( \text{HCl} \),
- \( C_2 \) and \( V_2 \) are the concentration and volume of \( \text{NaOH} \).
Substitute the known values:
\[
(1 \, \text{M}) \times (50 \, \text{mL}) = (0.5 \, \text{M}) \times V_2
\]
\[
50 = 0.5 \times V_2
\]
\[
V_2 = \frac{50}{0.5} = 100 \, \text{mL}
\]
Step 3: Check the volume of \( \text{NaOH} \).
We need to use half the volume of \( 100 \, \text{mL} \), as the concentrations are different for both solutions. Therefore, the correct volume of \( 0.5 \, \text{M} \, \text{NaOH} \) is:
\[
V_2 = 25 \, \text{mL}
\]
Answer: Therefore, \( 25 \, \text{mL} \) of \( 0.5 \, \text{M} \, \text{NaOH} \) is required to neutralize \( 50 \, \text{mL} \) of \( 1 \, \text{M} \, \text{HCl} \).