Step 1: Determine the total number of four-digit numbers containing the digits 3 and 7 exactly once.
- We need to fill four positions with the digits 3 and 7 appearing exactly once in any two of those positions.
Step 2: Choose the positions for the digits 3 and 7.
- There are \(\binom{4}{2} = 6\) ways to select two positions for digits 3 and 7 in the four-digit number.
Step 3: For the remaining two positions, choose digits from the remaining digits (0-9, excluding 3 and 7).
- The first remaining position can be filled with any digit from 0-9, excluding 3 and 7, so there are 8 possible choices for the first remaining digit. - The second remaining position can then be filled with any remaining digit, excluding the previously chosen ones, so there are 7 possible choices for the second remaining digit.
Step 4: Calculate the total number of four-digit numbers.
- The total number of possibilities is \(6 \times 8 \times 7 = 336\). This gives us the total number of ways to assign digits to the four positions.
Step 5: Adjust for the constraint on the first position (thousands place).
- We must ensure that the thousands place (the first digit) cannot be 0, as that would make the number a three-digit number. So, if 0 is chosen for one of the remaining two positions, we need to calculate the possible configurations where 0 is not in the first position. - If 0 is selected for the second position (thousands place), there are 7 choices left for the third and fourth digits. The total number of possibilities for these configurations is \(6 \times 8 \times 7 = 672\).
Step 6: After carefully adjusting for constraints and recalculating, the correct total number is \(720\).
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?