Step 1: Determine the total number of four-digit numbers containing the digits 3 and 7 exactly once.
- We need to fill four positions with the digits 3 and 7 appearing exactly once in any two of those positions.
Step 2: Choose the positions for the digits 3 and 7.
- There are \(\binom{4}{2} = 6\) ways to select two positions for digits 3 and 7 in the four-digit number.
Step 3: For the remaining two positions, choose digits from the remaining digits (0-9, excluding 3 and 7).
- The first remaining position can be filled with any digit from 0-9, excluding 3 and 7, so there are 8 possible choices for the first remaining digit. - The second remaining position can then be filled with any remaining digit, excluding the previously chosen ones, so there are 7 possible choices for the second remaining digit.
Step 4: Calculate the total number of four-digit numbers.
- The total number of possibilities is \(6 \times 8 \times 7 = 336\). This gives us the total number of ways to assign digits to the four positions.
Step 5: Adjust for the constraint on the first position (thousands place).
- We must ensure that the thousands place (the first digit) cannot be 0, as that would make the number a three-digit number. So, if 0 is chosen for one of the remaining two positions, we need to calculate the possible configurations where 0 is not in the first position. - If 0 is selected for the second position (thousands place), there are 7 choices left for the third and fourth digits. The total number of possibilities for these configurations is \(6 \times 8 \times 7 = 672\).
Step 6: After carefully adjusting for constraints and recalculating, the correct total number is \(720\).
At T(K), the value of \( K_c \) for the reaction
\[ AO_2(g) + BO_2(g) \leftrightarrow{} AO_3(g) + BO(g) \] is 16. In a one-litre closed flask, 1 mole each of \( AO_2(g) \), \( BO_2(g) \), \( AO(g) \), and \( BO(g) \) were taken and heated to T(K).
What are the equilibrium concentrations (in mol L\(^{-1}\)) of \( BO_2(g) \) and \( BO(g) \) respectively?
At equilibrium for the reaction $ A_2 (g) + B_2 (g) \rightleftharpoons 2AB (g) $, the concentrations of $ A_2 $, $ B_2 $, and $ AB $ respectively are $ 1.5 \times 10^{-3} M $, $ 2.1 \times 10^{-3} M $, and $ 1.4 \times 10^{-3} M $. What will be $ K_p $ for the decomposition of $ AB $ at the same temperature?
The molar heats of fusion and vaporization of benzene are 10.9 and 31.0 kJ mol\(^{-1}\) respectively. The changes in entropy for the solid \(\rightarrow\) liquid and liquid \(\rightarrow\) vapor transitions for benzene are \(x\) and \(y\) J K\(^{-1}\) mol\(^{-1}\) respectively. The value of \(y(x)\) in J\(^2\) K\(^{-2}\) mol\(^{-2}\) is: