Step 1: Analyze the original determinant, known to be a Vandermonde determinant.
- The determinant simplifies to \( (a-b)(b-c)(c-a) \), which is the product of the differences between the variables.
Step 2: Compare each option's determinant.
- Option (A), (B), and (C) give non-zero determinants as they involve transformations that preserve the structure of the Vandermonde determinant, and none of them result in linear dependency. - Option (D) is notably different because it results in a matrix with linearly dependent rows, as each element in the third row is the constant \(2\).
- This makes the determinant zero, which does not match the original determinant unless \(a = b = c\).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))