Analyze Each Reaction:
Reaction (A): The reaction conditions suggest Friedel-Crafts acylation using anhydrous \( \text{AlCl}_3 \) and a carboxylic acid chloride. This reaction should proceed correctly, forming the expected acylated aromatic product.
Reaction (B): In this reaction, \( \text{Pd/BaSO}_4 \) (Rosenmund reduction conditions) is used to reduce an acyl chloride to an aldehyde. This reaction is incorrect.
Reaction (C): This reaction involves a carboxylic acid reacting with CO and HCl under anhydrous conditions with \( \text{AlCl}_3 \) or CuCl. However, this is not a standard reaction for carboxylic acid conversion to an acyl chloride under these conditions, so this reaction is incorrect.
Reaction (D): The conditions involve the reaction of a benzene derivative with \( \text{CONH}_2 \) and HCl. However, these reagents are not compatible with producing an expected product under the given conditions, making this reaction incorrect.
Conclusion:
Only Reaction (A) is correct among the given reactions. Therefore, the number of correct reactions is 1, corresponding to Option (1).
Consider the gas phase reaction: \[ CO + \frac{1}{2} O_2 \rightleftharpoons CO_2 \] At equilibrium for a particular temperature, the partial pressures of \( CO \), \( O_2 \), and \( CO_2 \) are found to be \( 10^{-6} \, {atm} \), \( 10^{-6} \, {atm} \), and \( 16 \, {atm} \), respectively. The equilibrium constant for the reaction is ......... \( \times 10^{10} \) (rounded off to one decimal place).
Molten steel at 1900 K having dissolved hydrogen needs to be vacuum degassed. The equilibrium partial pressure of hydrogen to be maintained to achieve 1 ppm (mass basis) of dissolved hydrogen is ......... Torr (rounded off to two decimal places). Given: For the hydrogen dissolution reaction in molten steel \( \left( \frac{1}{2} {H}_2(g) = [{H}] \right) \), the equilibrium constant (expressed in terms of ppm of dissolved H) is: \[ \log_{10} K_{eq} = \frac{1900}{T} + 2.4 \] 1 atm = 760 Torr.
If all the words with or without meaning made using all the letters of the word "KANPUR" are arranged as in a dictionary, then the word at 440th position in this arrangement is:
Match List - I with List - II.