The number of alkali metal(s), from Li, K, Cs, $Rb$ having ionization enthalpy greater than $400\, kJ$ $mol ^{-1}$ and forming stable super oxide is
The number of alkali metal(s), from Li, K, Cs, $Rb$ having ionization enthalpy greater than $400\, kJ$ $mol ^{-1}$ and forming stable super oxide is
Show Hint
Correct Answer: 2
Solution and Explanation
K and Rb form stable superoxides, but Cs has an ionization enthalpy less than 400 kJ/mol.
Thus, the correct answer is 2, as K and Rb are the metals that meet the criteria.
Top Questions on Some Applications of d- and f-Block Elements
- Give explanation for each of the following observations:
(a) With the same d$^8$ orbital configuration, Mn$^{2+}$ ion is an oxidizing agent whereas Cr$^{2+}$ ion is a reducing agent.
(b) Atomic contraction is greater from element to element than much from lanthanides.
(c) Transition metals form large number of interstitial compounds with H, B, C, and N.- CBSE CLASS XII - 2025
- Chemistry
- Some Applications of d- and f-Block Elements
- Assertion (A): Cuprous salts are diamagnetic.
Reason (R): Cuprous ion has completely filled 3d-orbitals.- CBSE CLASS XII - 2025
- Chemistry
- Some Applications of d- and f-Block Elements
- Out of Fe$^{3+}$, Sc$^{3+}$, Cr$^{3+}$ and Co$^{3+}$ ions, the one which is colourless in aqueous solution is:
- CBSE CLASS XII - 2025
- Chemistry
- Some Applications of d- and f-Block Elements
- Examine the following observations: (a) Transition elements generally form coloured compounds.
(b) Zinc is not regarded as a transition element.- CBSE CLASS XII - 2025
- Chemistry
- Some Applications of d- and f-Block Elements
- The element having [Ar]$3d^{10}4s^1$ electronic configuration is
- CBSE CLASS XII - 2025
- Chemistry
- Some Applications of d- and f-Block Elements
Questions Asked in JEE Main exam
In the following \(p\text{–}V\) diagram, the equation of state along the curved path is given by \[ (V-2)^2 = 4ap, \] where \(a\) is a constant. The total work done in the closed path is:
- JEE Main - 2026
- Thermodynamics
Let \( ABC \) be a triangle. Consider four points \( p_1, p_2, p_3, p_4 \) on the side \( AB \), five points \( p_5, p_6, p_7, p_8, p_9 \) on the side \( BC \), and four points \( p_{10}, p_{11}, p_{12}, p_{13} \) on the side \( AC \). None of these points is a vertex of the triangle \( ABC \). Then the total number of pentagons that can be formed by taking all the vertices from the points \( p_1, p_2, \ldots, p_{13} \) is ___________.
- JEE Main - 2026
- Coordinate Geometry
- A voltage regulating circuit consisting of a Zener diode having breakdown voltage of $10\,\text{V}$ and maximum power dissipation of $0.4\,\text{W}$ is operated at $15\,\text{V}$. The approximate value of protective resistance in this circuit is ___ $\Omega$.
- JEE Main - 2026
- Semiconductor electronics: materials, devices and simple circuits
- Two point charges of \(1\,\text{nC}\) and \(2\,\text{nC}\) are placed at two corners of an equilateral triangle of side \(3\) cm. The work done in bringing a charge of \(3\,\text{nC}\) from infinity to the third corner of the triangle is ________ \(\mu\text{J}\). \[ \left(\frac{1}{4\pi\varepsilon_0}=9\times10^9\,\text{N m}^2\text{C}^{-2}\right) \]
- JEE Main - 2026
- Electrostatics
Consider the following two reactions A and B:
The numerical value of [molar mass of $x$ + molar mass of $y$] is ___.
- JEE Main - 2026
- Organic Chemistry
Concepts Used:
Properties of D Block Elements
- Multiple oxidation states- The oxidation states of d block elements show very few energy gaps; therefore, they exhibit many oxidation states. Also, the energy difference between s and d orbital is very less. Therefore both the electrons are involved in ionic and covalent bond formation, which ultimately leads to multiple oxidation states.
- Formation of complex compounds- Ligands show a binding behavior and can form so many stable complexes with the help of transition metals. This property is mainly due to:
- Availability of vacant d orbitals.
- Comparatively small sizes of metals.
- Hardness- Transition elements are tough and have high densities because of the presence of unpaired electrons.
- Melting and boiling points- Melting and boiling points of transition are very high because of the presence of unpaired electrons and partially filled d orbitals. They form strong bonds and have high melting and boiling points.
- Atomic radii- The atomic and ionic radius of the transition elements decreases as we move from Group 3 to group 6. However, it remains the same between group 7 and group 10, and from group 11 to group 12 increases.
- Ionization enthalpy- The ionization enthalpies of the transition elements are generally on the greater side as compared to the S block elements