The moment of inertia of a solid sphere about its diameter is given by:
\[
I_{\text{solid sphere}} = \frac{2}{5} m r^2,
\]
where \( m \) is the mass and \( r \) is the radius.
For a solid sphere, the moment of inertia is \( 20 \, \text{kg m}^2 \). Thus:
\[
\frac{2}{5} m r^2 = 20.
\]
From this, we can solve for \( m r^2 \):
\[
m r^2 = \frac{5 \times 20}{2} = 50.
\]
For a thin spherical shell, the moment of inertia about its diameter is given by:
\[
I_{\text{shell}} = \frac{2}{3} m r^2.
\]
Substitute \( m r^2 = 50 \):
\[
I_{\text{shell}} = \frac{2}{3} \times 50 = 33.3 \, \text{kg m}^2.
\]
Thus, the correct answer is \( 33.3 \, \text{kg m}^2 \).