To solve the problem, we need to identify the molecule in which the central atom possesses exactly one lone pair of electrons in its valence shell.
1. Analyzing the Molecules:
- CH₄ (Methane): Carbon forms 4 sigma bonds with hydrogen atoms. It has no lone pairs.
- BF₃ (Boron trifluoride): Boron forms 3 bonds with fluorine atoms and has an incomplete octet with no lone pairs.
- BeCl₂ (Beryllium chloride): Beryllium forms 2 bonds and also has an incomplete octet with no lone pairs.
- NH₃ (Ammonia): Nitrogen forms 3 bonds with hydrogen atoms and has 1 lone pair of electrons in its valence shell.
2. Conclusion:
Among the given molecules, only NH₃ has a lone pair on the central atom (nitrogen).
Final Answer:
The molecule is $ \text{NH}_3 $