The reaction of HI with ethers follows acidic cleavage, where the more hindered alkyl group retains the OH, while the less hindered group forms an iodoalkane.
- The larger group (2-methylbutyl) forms 2-methylbutan-1-ol.
- The smaller group (ethyl) forms iodoethane.
Thus, the major products are 2-methylbutan-1-ol and iodoethane.
For the reaction:
\[ 2A + B \rightarrow 2C + D \]
The following kinetic data were obtained for three different experiments performed at the same temperature:
\[ \begin{array}{|c|c|c|c|} \hline \text{Experiment} & [A]_0 \, (\text{M}) & [B]_0 \, (\text{M}) & \text{Initial rate} \, (\text{M/s}) \\ \hline I & 0.10 & 0.10 & 0.10 \\ II & 0.20 & 0.10 & 0.40 \\ III & 0.20 & 0.20 & 0.40 \\ \hline \end{array} \]
The total order and order in [B] for the reaction are respectively: