The dimension of $ \sqrt{\frac{\mu_0}{\epsilon_0}} $ is equal to that of: (Where $ \mu_0 $ is the vacuum permeability and $ \epsilon_0 $ is the vacuum permittivity)
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
| \([A]\) (mol/L) | \(t_{1/2}\) (min) |
|---|---|
| 0.100 | 200 |
| 0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
A solution of aluminium chloride is electrolyzed for 30 minutes using a current of 2A. The amount of the aluminium deposited at the cathode is _________
Dimensional Analysis is a process which helps verify any formula by the using the principle of homogeneity. Basically dimensions of each term of a dimensional equation on both sides should be the same.
Limitation of Dimensional Analysis: Dimensional analysis does not check for the correctness of value of constants in an equation.
Let us understand this with an example:
Suppose we don’t know the correct formula relation between speed, distance and time,
We don’t know whether
(i) Speed = Distance/Time is correct or
(ii) Speed =Time/Distance.
Now, we can use dimensional analysis to check whether this equation is correct or not.
By reducing both sides of the equation in its fundamental units form, we get
(i) [L][T]-¹ = [L] / [T] (Right)
(ii) [L][T]-¹ = [T] / [L] (Wrong)
From the above example it is evident that the dimensional formula establishes the correctness of an equation.