Question:

The IUPAC name of the compound, $ {{C}_{2}}{{H}_{5}}NHCOC{{H}_{3}} $ is:

Updated On: Aug 17, 2024
  • N-acetyl emanamme
  • n-ethanoyl ethanamine
  • N-ethyl-N-methyl acetamide.

  • all of the above
Hide Solution
collegedunia
Verified By Collegedunia

The Correct Option is C

Solution and Explanation

The correct option is(B): N-ethyl-N-methyl acetamide.

The given compound C2​H5​NHCOCH3​ can be broken down into its constituent parts:

  1. C2​H5​ represents an ethyl group.
  2. NHCOCH3​ represents a functional group consisting of an amide group (NHCO) attached to a methyl group (CH3​).

When naming this compound according to IUPAC nomenclature, we follow these steps:

Identify the longest carbon chain containing the functional groups. In this case, there is only one carbon atom, so it's not a chain.

Identify and name the substituents (groups) attached to the carbon chain.

  • The ethyl group (C2​H5​) is a substituent.
  • The NHCOCH3​ group is also a substituent. We can name it as "N-methyl ethanamide."

Combine the substituent names in alphabetical order, along with the main functional group name. Use hyphens to separate the names.

Applying these steps:

  • The substituent "ethyl" comes before "methyl" alphabetically.
  • The main functional group is an amide, so we use the suffix "-amide."

Combining these, we get the IUPAC name as "N-ethyl-N-methyl ethanamide."

However, it seems that there might be a slight typo in the answer you provided. The correct answer should be "N-ethyl-N-methyl acetamide" instead of "N-ethyl ethanamide." The functional group NHCOCH3​ corresponds to an acetamide group, not a simple amide. The "acetamide" part comes from the acetate structure (CH3​CO−).

So, the correct IUPAC name is "N-ethyl-N-methyl acetamide."

Was this answer helpful?
2
0

Concepts Used:

Nomenclature of Organic Compounds

Nomenclature of Organic Compounds can be defined as the systematic approach to name different organic compounds present in the world. In order to avoid some long and tedious common names in the general communication, the officials of the International Union of Pure and Applied Chemistry (IUPAC) have formulated some structured way of naming the organic compounds.

IUPAC Nomenclature:

International Union of Pure and Applied Chemistry (IUPAC) introduced the classical nomenclature for the organic compounds systematically. Some rules were introduced such that every molecule has an individual name for its different structures.

The general skeleton of an IUPAC nomenclature is given as:

Primary prefix + word root + primary suffix + secondary suffix

Guidelines set by IUPAC:

  1. The Longest Chain Rule
  2. The Lowest Set of Locants
  3. Multiple instances of the same substituent
  4. Naming of different substituents
  5. The naming of different substituents present at the same positions
  6. Naming Complex Substituents