Question:

The geometry of paramagnetic nickel complex [NiCl₄]²⁻ is:

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d⁸ paramagnetic prefers tetrahedral.

  • tetrahedral

  • octahedral

  • square planar

  • distorted octahedral

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The Correct Option is A

Solution and Explanation

Ni²⁺ in [NiCl₄]²⁻ is 3d⁸ and paramagnetic, hence adopts tetrahedral geometry. Square planar is typical for diamagnetic d⁸ complexes.

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