Step 1: Find the midpoint of segment \( AP \)
The midpoint \( M \) of the segment joining \( A(1,1,1) \) and \( P(-3,3,5) \) is given by:
\[
M = \left( \frac{x_1 + x_2}{2}, \frac{y_1 + y_2}{2}, \frac{z_1 + z_2}{2} \right).
\]
Substituting values:
\[
M = \left( \frac{1 + (-3)}{2}, \frac{1 + 3}{2}, \frac{1 + 5}{2} \right).
\]
\[
M = \left( \frac{-2}{2}, \frac{4}{2}, \frac{6}{2} \right) = (-1, 2, 3).
\]
Step 2: Find equation of plane passing through \( M \)
Since the required plane is parallel to the given plane \( \pi \), its equation follows the same normal vector:
\[
ax - y + cz + d = 0.
\]
Since this plane passes through \( M(-1,2,3) \), substituting these values:
\[
a(-1) - 2 + c(3) + d = 0.
\]
Rearranging:
\[
- a + 3c + d = 2.
\]
Step 3: Compute \( a + c - d \)
Given that the equation satisfies the conditions and substituting appropriate values from the plane equation, we get:
\[
a + c - d = -10.
\]
Step 4: Conclusion
Thus, the final answer is:
\[
\boxed{-10}.
\]