In acidic medium, the equivalent weight of Potassium permanganate (\( \text{KMnO}_4 \)) is calculated based on its change in oxidation state. Potassium permanganate undergoes a reduction from +7 to +2 oxidation state, and since 5 electrons are involved, the equivalent weight of \( \text{KMnO}_4 \) is 31.6 g/equiv.