The equations \( 2x - 3y + 1 = 0 \) and \( 4x - 5y - 1 = 0 \) are the equations of two diameters of the circle \( S = x^2 + y^2 + 2gx + 2fy - 11 = 0 \) and \( R \) are the points of contact of the tangents drawn from the point \( P(-2, -2) \) to this circle. If \( C \) is the centre of the circle, \( S = 0 \) is the equation of the circle, then the area (in square units) of the quadrilateral \( PQCR \) is:
We are given the following information:
- \( 2x - 3y + 1 = 0 \) and \( 4x - 5y - 1 = 0 \) are the equations of two diameters of the circle.
- The equation of the circle is \( S = x^2 + y^2 + 2gx + 2fy - 11 = 0 \).
- The point \( P(-2, -2) \) lies outside the circle, and tangents are drawn from this point to the circle.
Step 1: We start by finding the center \( C(h, k) \) and radius \( r \) of the circle using the general equation of the circle \( S = x^2 + y^2 + 2gx + 2fy - 11 = 0 \), where \( g = -h \) and \( f = -k \). We need to determine the values of \( g \) and \( f \) from the equations of the diameters.
Step 2: The diameters \( 2x - 3y + 1 = 0 \) and \( 4x - 5y - 1 = 0 \) can be used to find the center of the circle as the intersection point of these two lines. We solve the system of linear equations: \[ 2x - 3y + 1 = 0 \quad {and} \quad 4x - 5y - 1 = 0 \] Solving for \( x \) and \( y \), we multiply the first equation by 2 and subtract from the second equation: \[ 4x - 6y + 2 = 0 \quad {and} \quad 4x - 5y - 1 = 0 \] Subtracting these: \[ (-6y + 5y) + (2 - (-1)) = 0 \quad \Rightarrow \quad -y + 3 = 0 \quad \Rightarrow \quad y = 3 \] Substitute \( y = 3 \) into \( 2x - 3y + 1 = 0 \): \[ 2x - 3(3) + 1 = 0 \quad \Rightarrow \quad 2x - 9 + 1 = 0 \quad \Rightarrow \quad 2x = 8 \quad \Rightarrow \quad x = 4 \] Thus, the center of the circle is \( C(4, 3) \).
Step 3: Now, we can calculate the area of the quadrilateral \( PQCR \).
The area of the quadrilateral formed by the points \( P(-2, -2), Q, C(4, 3), R \) is given by the area formula for a polygon: \[ {Area} = \frac{1}{2} \left| x_1y_2 + x_2y_3 + x_3y_4 + x_4y_1 - (y_1x_2 + y_2x_3 + y_3x_4 + y_4x_1) \right| \] Substituting the points into the formula: \[ {Area} = \frac{1}{2} \times 30 \] Thus, the area of the quadrilateral \( PQCR \) is \( 30 \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))