Let \( \hat{a} \) be a unit vector perpendicular to the vectors \[ \mathbf{b} = \hat{i} - 2\hat{j} + 3\hat{k} \quad \text{and} \quad \mathbf{c} = 2\hat{i} + 3\hat{j} - \hat{k}, \] \(\text{and makes an angle of}\) \( \cos\left( -\frac{1}{3} \right) \) \(\text{with the vector}\) \( \hat{i} + \alpha \hat{j} + \hat{k} \). \(\text{If}\) \( \hat{a} \) \(\text{makes an angle of}\) \( \frac{\pi}{3} \) \(\text{with the vector}\) \( \hat{i} + \alpha \hat{j} + \hat{k} \), then the value of \( \alpha \) \(\text{is:}\)