In the adjoining figure, TP and TQ are tangents drawn to a circle with centre O. If $\angle OPQ = 15^\circ$ and $\angle PTQ = \theta$, then find the value of $\sin 2\theta$. 
What is the angle between the hour and minute hands at 4:30?
Find the unknown frequency if 24 is the median of the following frequency distribution:
\[\begin{array}{|c|c|c|c|c|c|} \hline \text{Class-interval} & 0-10 & 10-20 & 20-30 & 30-40 & 40-50 \\ \hline \text{Frequency} & 5 & 25 & 25 & \text{$p$} & 7 \\ \hline \end{array}\]