The de Broglie wavelength \( \lambda \) associated with a particle (in this case, an electron) is given by the formula:
\[
\lambda = \frac{h}{p}
\]
where:
- \( h \) is Planck's constant (\( 6.626 \times 10^{-34} \, {J·s} \)),
- \( p \) is the momentum of the particle.
The momentum \( p \) of an electron accelerated by a potential \( V \) is:
\[
p = \sqrt{2 m_e e V}
\]
where:
- \( m_e \) is the mass of the electron (\( 9.11 \times 10^{-31} \, {kg} \)),
- \( e \) is the charge of the electron (\( 1.6 \times 10^{-19} \, {C} \)),
- \( V \) is the potential difference (in this case, 81 V).
Substituting these values into the formula for \( p \):
\[
p = \sqrt{2 \times 9.11 \times 10^{-31} \times 1.6 \times 10^{-19} \times 81}
\]
Now, the de Broglie wavelength \( \lambda \) can be calculated using the above formula. For this case, the wavelength \( \lambda \) will be in the range of X-rays.
Therefore, the correct answer is:
\[
\boxed{{D) X-rays}}
\]