Question:

The crystal field theory is successful in explaining which of the following?

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Crystal field theory explains colour and magnetic properties but not covalent bonding.
Updated On: May 20, 2025
  • I, II, III only
  • II, III, IV only
  • III, IV, V only
  • I, III, IV only
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The Correct Option is B

Solution and Explanation

Crystal field theory (CFT) considers ligands as point charges and focuses on the electrostatic interaction between metal and ligand.
CFT is successful in explaining: 
II. Formation and structures of complexes
III. Colour (due to d-d transition)
IV. Magnetic properties (due to electron pairing/unpairing in d orbitals)
It does not explain I (ligands as point charges is an assumption, not an outcome)
It also fails to explain V (covalent character), which is covered by Molecular Orbital Theory

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