Ethanal to But-2-enal
Propanoic acid to Ethane
An alkene A with molecular formula C\(_6\)H\(_{10}\) on ozonolysis gives a mixture of two compounds B and C. Compound B gives a positive Fehling's test and also reacts with iodine and NaOH solution. Compound C does not give Fehling's test but forms iodoform. Identify the compounds A, B, and C.
Amines have a lone pair of electrons on the nitrogen atom, due to which they behave as Lewis bases. Greater the value of \( K_b \) or smaller the value of \( pK_b \), stronger is the base. Amines are more basic than alcohols, ethers, esters, etc. The basic character of aliphatic amines should increase with the increase of alkyl substitution. However, it does not occur in a regular manner, as a secondary aliphatic amine is unexpectedly more basic than a tertiary amine in aqueous solutions. Aromatic amines are weaker bases than ammonia and aliphatic amines. Electron-releasing groups such as \( -CH_3 \), \( -NH_2 \), etc., increase the basicity, while electron-withdrawing substituents such as \( -NO_2 \), \( -CN \), halogens, etc., decrease the basicity of amines. The effect of these substituents is more pronounced at the para-position than at the meta-position.
(a) Arrange the following in increasing order of their basic character. Give reason:
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