Sum of \(\pi\)-bonds present in peroxodisulphuric acid and pyrosulphuric acid is___________
Count π-bonds in double bonds (C=O, S=O, etc.) while analyzing structures of acids.
• Peroxodisulphuric acid: Structure: \[ H - O - S(=O)_2 - O - O - S(=O)_2 - O - H \] Number of \(\pi\)-bonds = 4 (two in each \(\text{SO}_3\) group)
• Pyrosulphuric acid: Structure: \[ H - O - S(=O)_2 - O - S(=O)_2 - O - H \] Number of \(\pi\)-bonds = 4 (two in each \(\text{SO}_3\) group).
Total \(\pi\)-bonds = \(4 + 4 = 8\).
Given below are two statements.
In the light of the above statements, choose the correct answer from the options given below:
Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of $\mathrm{p} \pi-\mathrm{p} \pi$ bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of the above statements, choose the correct answer from the options given below:
Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. $(\mathrm{B}<\mathrm{Al}),(\mathrm{Al}<\mathrm{Ga}),(\mathrm{Ga}<\mathrm{In})$ and $(\mathrm{In}<\mathrm{Tl})$ Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius $\left(\mathrm{M}^{3+}\right)$ than the other one. The atomic number of the element (X) is
If all the words with or without meaning made using all the letters of the word "KANPUR" are arranged as in a dictionary, then the word at 440th position in this arrangement is:
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]