Question:

Structure of M
Structure of M is

Updated On: Apr 11, 2025
  • Ph-C=CH
  • Ph-C=C-CH3
  • H3C-C=CH
  • H3C-C≡C-CH3
Hide Solution
collegedunia
Verified By Collegedunia

The Correct Option is A

Solution and Explanation

Detailed Explanation of the Structure of M: 

We are given several possible structures and asked to identify the correct one based on some underlying reaction or context (often elimination, rearrangement, or resonance stabilization in organic chemistry).

Let’s analyze each option:

  1. Option (A): Ph–C=CH2
    This is styrene or phenylethene. It contains a phenyl group (Ph–) directly attached to a vinyl group (–CH=CH2).
    The double bond is conjugated with the aromatic ring, providing resonance stabilization.
    This conjugation lowers the overall energy of the molecule and makes it more stable than isolated alkenes.
    Such stability often leads to it being the major product in elimination reactions where conjugated systems are favored.
  2. Option (B): Ph–C≡C–CH3
    This is an alkyne with a phenyl ring. Though alkynes are stable, they lack the same conjugative stabilization with the ring that alkenes like styrene have.
    No conjugation is possible between the phenyl ring and triple bond (as π systems of alkynes and benzenes are orthogonal), so it's less stable.
  3. Option (C): CH3–C=CH2
    This is a simple terminal alkene without any resonance stabilization.
    It lacks both conjugation and aromatic influence, so it is less stable than option (A).
  4. Option (D): CH3–C≡C–CH3
    This is butyne (an internal alkyne), which is a linear molecule without any aromatic or conjugated effects. Again, no special stabilization is present here.

Conclusion:
Among all the options, option (A) (Ph–CH=CH2) is the most stable and plausible structure due to extended conjugation with the phenyl ring. This stabilizes the molecule via resonance, making it the most likely structure of compound M.

Correct Answer: (A): Ph–CH=CH2

Was this answer helpful?
0
0

Concepts Used:

Aromatic hydrocarbon

Aromatic hydrocarbons, sometimes known as arenes, are aromatic organic molecules made up entirely of carbon and hydrogen. In aromatic compounds a benzene ring which is named after the simple aromatic chemical benzene, or a phenyl group when part of a larger structure, is the configuration of six carbon atoms.

Read More: Aromaticity

Reactions of Aromatic Hydrocarbons:

1. Aromatic Substitution Reactions

This reaction involves the replacement of one substituent on the ring of an aromatic hydrocarbon, commonly a hydrogen atom, by a different substituent group.

The common types of aromatic substitution reactions are:

  • Nucleophilic aromatic substitution reactions
  • Electrophilic aromatic substitution reactions
  • Radical nucleophilic aromatic substitution reactions

2. Coupling Reactions

In these types of reactions, the coupling of two fragments that have a radical nature is achieved with the help of a metal catalyst