Spin only magnetic moment of the compound $Hg[Co(SCN)_4] $ is
- $\sqrt 3 $
- $\sqrt {15} $
- $\sqrt {24} $
- $\sqrt {8} $
The Correct Option is B
Solution and Explanation
Top Questions on Bonding in Metal Carbonyls
In the following species, how many species have the same magnetic moment?
(i) Cr\(^{2+}\)
(ii) Mn\(^{3+}\)
(iii) Ni\(^{2+}\)
(iv) Sc\(^{2+}\)
(v) Zn\(^{2+}\)
(vi) V\(^{3+}\)
(vii) Ti\(^{4+}\)
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The left and right compartments of a thermally isolated container of length $L$ are separated by a thermally conducting, movable piston of area $A$. The left and right compartments are filled with $\frac{3}{2}$ and 1 moles of an ideal gas, respectively. In the left compartment the piston is attached by a spring with spring constant $k$ and natural length $\frac{2L}{5}$. In thermodynamic equilibrium, the piston is at a distance $\frac{L}{2}$ from the left and right edges of the container as shown in the figure. Under the above conditions, if the pressure in the right compartment is $P = \frac{kL}{A} \alpha$, then the value of $\alpha$ is ____
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Concepts Used:
Bonding in Metal Carbonyls
The metal-carbon bond possesses both the σ and π character in a metal carbonyl. The synergic effect produced by the metal-ligand bond strengthens the bond between the carbonyl molecule and the metal. The types of bonding that exist in metal carbonyls are as follows:
Structure of Metal Carbonyls:
- Due to the donation of electrons by the carbonyl molecules to the vacant orbitals of the metal, a metal-carbon σ bond is formed.
- Due to the donation of a pair of electrons from a filled d orbital metal into the vacant anti bonding π orbital of carbonyl ligand, a metal-carbon π bond is formed.
Stability of Coordination Compounds:
They are found to dissociate in various solutions. The stability of a coordination compound in a solution mainly depends on the degree of association between the two species involved in the state of equilibrium. For the formation of the compound quantitatively the stability of any complex is given by the magnitude of the equilibrium constant. For instance,
A + 4B→ AB4