Step 1: {Hybridisation of the Central Atom}
In sp\(^3\) d\(^2\) hybridisation, the central atom undergoes hybridisation by combining one \(s\), three \(p\), and two \(d\) orbitals, resulting in six hybrid orbitals. This hybridisation occurs in species where the central atom is bonded to six other atoms.
Step 2: {Analysis of Compounds}
In BrF\(_5\), bromine undergoes sp\(^3\) d\(^2\) hybridisation, as it is bonded to five fluorine atoms.
In SF\(_6\), sulfur undergoes sp\(^3\) d\(^2\) hybridisation, as it is bonded to six fluorine atoms.
In [CrF\(_6\)]\(^{3-}\), chromium undergoes sp\(^3\) d\(^2\) hybridisation due to the bonding with six fluoride ions.
In PF\(_5\), phosphorus undergoes sp\(^3\) hybridisation, as it is bonded to five fluorine atoms, not six.
Thus, the correct answer is (D).
Concentrated nitric acid is labelled as 75% by mass. The volume in mL of the solution which contains 30 g of nitric acid is:
Given: Density of nitric acid solution is 1.25 g/mL.
Arrange the following in increasing order of solubility product:
\[ {Ca(OH)}_2, {AgBr}, {PbS}, {HgS} \]
Match List - I with List - II.
List - I (Saccharides) List - II (Glycosidic linkages found)
(A) Sucrose (I) \( \alpha 1 - 4 \)
(B) Maltose (II) \( \alpha 1 - 4 \) and \( \alpha 1 - 6 \)
(C) Lactose (III) \( \alpha 1 - \beta 2 \)
(D) Amylopectin (IV) \( \beta 1 - 4 \)
Choose the correct answer from the options given below:
Match List - I with List - II.
List - I (Complex) | List - II (Hybridisation) |
---|---|
(A) \([\text{CoF}_6]^{3-}\) | (I) \( d^2 sp^3 \) |
(B) \([\text{NiCl}_4]^{2-}\) | (II) \( sp^3 \) |
(C) \([\text{Co(NH}_3)_6]^{3+}\) | (III) \( sp^3 d^2 \) |
(D) \([\text{Ni(CN}_4]^{2-}\) | (IV) \( dsp^2 \) |
Choose the correct answer from the options given below: