Solve the equation \(\begin{vmatrix} x+a &x &x \\ x &x+a &x \\ x&x &x+a \end{vmatrix}=0\) , a≠0
\(\begin{vmatrix} x+a &x &x \\ x &x+a &x \\ x&x &x+a \end{vmatrix}=0\)
Applying R1\(\rightarrow\)R1+R2+R3, we get:
\(\begin{vmatrix} 3x+a &3x+a &3x+a \\ x &x+a &x \\ x&x &x+a \end{vmatrix}=0\)
\(\Rightarrow\)(3x+a)\(\begin{vmatrix} 1 &1 &1 \\ x &x+a &x \\ x&x &x+a \end{vmatrix}=0\)
Applying C2\(\rightarrow\)C2-C1 and C3\(\rightarrow\)C3-C1, we have:
(3x+a)\(\begin{vmatrix} 1&0 &0 \\ x& a &0 \\ x&0 &a \end{vmatrix}\)=0
Expanding along R1,we have:
(3x+a)[1\(\times\)a2]=0
\(\Rightarrow\)a2(3x+a)=0
But a≠0,
Therefore we have
3x+a=0
\(\Rightarrow x=-\frac{a}{3}\)
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.