Question:

Sodium in liquid ammonia initiates the polymerization of which of the following monomers?

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Sodium in liquid ammonia is known for its ability to generate free radicals, which are essential in the polymerization of nitriles and other reactive monomers.
Updated On: May 14, 2025
  • CN
  • CH\(_3\)C\(_6\)H\(_5\)
  • Cl
  • H\(_2\)C=CH\(_2\)
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The Correct Option is A

Solution and Explanation

- Sodium in liquid ammonia is typically used to initiate the polymerization of compounds that are capable of forming free radicals. The polymerization of nitriles, such as acrylonitrile (C\(_3\)H\(_3\)N), is commonly initiated in liquid ammonia, and the monomer with the nitrile group (CN) is the correct choice.
- The other compounds (option 2, 3, and 4) are either not suitable for polymerization in this condition or are not typical monomers used in this process.
Thus, the correct answer is (1) CN.
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